全文获取类型
收费全文 | 36599篇 |
免费 | 4923篇 |
国内免费 | 2401篇 |
专业分类
电工技术 | 808篇 |
综合类 | 2545篇 |
化学工业 | 9984篇 |
金属工艺 | 623篇 |
机械仪表 | 1204篇 |
建筑科学 | 453篇 |
矿业工程 | 1240篇 |
能源动力 | 563篇 |
轻工业 | 10667篇 |
水利工程 | 157篇 |
石油天然气 | 1992篇 |
武器工业 | 165篇 |
无线电 | 2233篇 |
一般工业技术 | 1340篇 |
冶金工业 | 1468篇 |
原子能技术 | 537篇 |
自动化技术 | 7944篇 |
出版年
2024年 | 125篇 |
2023年 | 590篇 |
2022年 | 1131篇 |
2021年 | 1377篇 |
2020年 | 1435篇 |
2019年 | 1208篇 |
2018年 | 1127篇 |
2017年 | 1277篇 |
2016年 | 1394篇 |
2015年 | 1647篇 |
2014年 | 2307篇 |
2013年 | 2718篇 |
2012年 | 3695篇 |
2011年 | 3313篇 |
2010年 | 2317篇 |
2009年 | 2119篇 |
2008年 | 1988篇 |
2007年 | 2459篇 |
2006年 | 2126篇 |
2005年 | 1677篇 |
2004年 | 1365篇 |
2003年 | 1210篇 |
2002年 | 912篇 |
2001年 | 738篇 |
2000年 | 651篇 |
1999年 | 521篇 |
1998年 | 422篇 |
1997年 | 373篇 |
1996年 | 293篇 |
1995年 | 269篇 |
1994年 | 192篇 |
1993年 | 160篇 |
1992年 | 161篇 |
1991年 | 120篇 |
1990年 | 97篇 |
1989年 | 77篇 |
1988年 | 53篇 |
1987年 | 54篇 |
1986年 | 37篇 |
1985年 | 37篇 |
1984年 | 36篇 |
1983年 | 21篇 |
1982年 | 20篇 |
1981年 | 15篇 |
1980年 | 15篇 |
1979年 | 8篇 |
1978年 | 6篇 |
1977年 | 6篇 |
1959年 | 6篇 |
1951年 | 11篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
51.
52.
Mark W. Hlawitschka Jonas Schulz Dominic Wirz Jan Schäfer Alexander Keller Hans-Jörg Bart 《化学,工程师,技术》2020,92(7):914-925
The digitization of extraction columns requires a profound knowledge of the present hydrodynamics/mass transport interaction as well as appropriate measurement techniques for the detection of relevant input and target values. In this article, the different techniques for droplet size distribution as well as concentration determination are presented and new methods for online evaluation are discussed. In combination with the simulation of droplet size, holdup and solute concentration distribution, an online-capable process tool for controlling and optimizing extraction columns will be obtained. 相似文献
53.
萃取塔因生产能力大、占地面积小、密闭性好等优点,在石油、化工、生物、医药和环境工程等多领域被广泛应用。本文从以下几个方面介绍了萃取塔近些年的研究进展:综述了传统萃取塔(脉冲萃取塔、转盘塔与Kühni塔等)的水力学、轴向扩散与传质模型的发展,分析比较了表面张力、传质方向、放大效应等因素对模型的影响;介绍了计算流体动力学(CFD)在萃取塔中单液滴、单相流模拟、液-液两相流模拟、外加能量模拟、与群体平衡模型(PBM)耦合模拟中的应用进展;介绍了国内外设计开发的新型萃取塔,包括改变传统塔的内构件和引入多种外场能量等方式来强化相间传质。研究表明,将先进实验研究方法、准确经验模型和可靠理论计算相结合,将会是萃取塔研究的重要手段和方向。 相似文献
54.
Carlos Eduardo de Ara jo Padilha Juliana Chris Silva de Azevedo Francisco Canind de Sousa J nior S rgio Dantas de Oliveira J nior Domingos Fabiano de Santana Souza Jackson Ara jo de Oliveira Gorete Ribeiro de Macedo Everaldo Silvino dos Santos 《中国化学工程学报》2018,26(12):2471-2476
In this study the potential of cloud point extraction formed by a non-ionic surfactant was used in order to separate polyphenols from industrial residues of camu-camu. The effects of operational conditions of the cloud point extraction (CPE) on the polyphenol recovery and volumetric ratio were investigated. The results showed a maximum recovery of 95.71% that was obtained using 7.0 wt% Triton X-114, native pH (3.25), and 80 wt% polyphenol extract at 30 °C. The use of cloud point extraction was successful to recover the polyphenols from agroindustrial residue since it is a simple as well as of low-cost technique. 相似文献
55.
This article deals with the evaluation of pressure drop and consumption of energy for a steady-state solvent extraction in a horizontal pulsed sieve-plate column, which are important for the design and optimization of the periodic-flow processes for industrial applications. In this study, the pressure drop and the position of loading points are investigated. Moreover, a mathematical evaluation on the energy consumption in the case of a pulsed flow is conducted, and besides the influence of pulsation intensity, the effect of geometrical parameters including the plate spacing and plate-free area is investigated as well. The results of this study are helpful for optimization of column geometry targeted to higher performance and lower energy consumption. 相似文献
56.
Daniel Whittaker Andreas Geist Giuseppe Modolo Robin Taylor Mark Sarsfield Andreas Wilden 《溶剂提取与离子交换》2018,36(3):223-256
Over the last decade there has been much interest in the applications of diglycolamide (DGA) ligands for the extraction of the trivalent lanthanide and actinide ions from PUREX high active raffinates or dissolved spent nuclear fuel. Of the DGAs, the N,N,N’,N’-tetraoctyldiglycolamide (TODGA) is the best known and most widely studied. A number of new actinide separation processes have been proposed based on extraction with TODGA. This review covers TODGA-based processes and extraction data, specifically focusing on how phase modifiers have been used to increase metal loading and thus enhance the operating process envelopes. Effects of third phase formation and the organic phase speciation are reviewed in this context. Relevant aspects of the extraction chemistry of important solvents (TODGA-modifier-diluent combinations) are described and their performances demonstrated by a consideration of the published flowsheet tests. It is seen that modifiers are successfully enabling the use of TODGA in actinide separation processes but to date the identification and testing of suitable modifiers has been rather empirical. There is a growing understanding of the fundamental chemistry occurring in the organic phase and how that affects extractant speciation and metal loading capacity but studies are still needed if TODGA-based flowsheets are to become an industrially deployable option for minor actinide (MA) recovery processes. 相似文献
57.
Coproduction of Ethyl Acetate and n‐Butyl Acetate by Using a Reactive Dividing‐Wall Column 下载免费PDF全文
The performance of the reactive distillation dividing‐wall column for coproduction of ethyl acetate and butyl acetate was experimentally studied. n‐Butanol and ethanol are raw reaction materials that react with acetic acid in the reaction zone to produce n‐butyl acetate and ethyl acetate, respectively. n‐Butyl acetate is not only a product, but also acts to remove water generated by the esterification reactions. The effects of various parameters, such as catalyst loading per stage, reflux ratio, liquid split and molar feed ratios, ethyl acetate/n‐butyl acetate purity, pressure drop, and total energy consumption, are investigated. Results show that ethanol could be completely converted and the products could be easily separated, which shows great industrial application potential in the coproduction of ethyl acetate and n‐butyl acetate. 相似文献
58.
Dynamic Performance of a Complex Distillation System to Separate a Five‐Component Hydrocarbon Mixture 下载免费PDF全文
Juan Gabriel Segovia Hernández Fernando Israel Gómez-Castro Eduardo Sánchez-Ramírez 《化学工程与技术》2018,41(10):2053-2065
Distillation is one of the most used separation processes in chemical industry, although it is a highly energy‐intensive operation. For multicomponent distillation, complex structures have been proposed in previous works, which may allow energy savings. Nevertheless, it is mandatory to understand the dynamic characteristics of such complex structures. In this work, the dynamic performance of a dividing‐wall‐based structure for the separation of a five‐component mixture is studied. A sensitivity analysis is performed on the structure in terms of the interlinking streams, performing a singular value decomposition analysis to selected cases with different operational conditions. The designs with the lowest energy duties also showed the best open‐loop properties. 相似文献
59.
针对齿轮故障特征微弱,在强背景噪声下难以有效提取的问题,提出了一种改进奇异谱分解(ISSD)结合奇异值分解(SVD)的齿轮故障特征提取方法。针对奇异谱分解(SSD)算法中模态参数需凭经验选取的缺陷,基于散布熵优化算法对SSD算法进行了改进,在得到既定的一组奇异谱分量的基础上,根据峭度值最大准则筛选出了最佳奇异谱分量并进行了SVD处理,采用奇异值能量标准谱自适应地确定了信号重构阶数以还原信号和提高降噪效果。最后对信号进行包络解调以提取齿轮故障特征,将所提方法运用到仿真信号和齿轮实测信号中,并同传统包络谱、SSD包络谱以及经验模态分解结合SVD(EMD-SVD)方法进行了对比分析,结果表明,所提方法的降噪和特征提取效果更佳,能够更加有效地实现齿轮故障的判别。 相似文献
60.
全球性的水资源短缺及环境污染问题,使得工业废水处理、海水淡化、高价值溶质综合利用的需求日益迫切。膜蒸馏结晶过程可以充分利用低品质热源,实现高纯度水溶剂分离、盐分结晶制备,对于实现分离过程零排放和协同增效有重要意义。同时,膜蒸馏结晶也可以与多级闪蒸,多效精馏、纳滤、正向渗透、反渗透等过程进行耦合,进一步提高整体分离效率。此外,该过程对于调控晶体外部形貌,制备晶体尺寸分布集中、流动性好的晶体产品也有积极作用。基于此,针对膜蒸馏结晶原理、过程调控机制以及创新过程应用几个方面开展论述,总结了膜蒸馏结晶技术在高效分离、结晶过程精准控制等领域的关键问题和发展趋势。 相似文献